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- W2065430049 abstract "Using the self-consistent field theory (SCFT) in spherical unit cells of various dimensionalities, D, a phase diagram of a diblock, A-b-B, is calculated in 5 dimensional space, d = 5. This is an extension of a previous work for d = 4. The phase diagram is parameterized by the chain composition, f, and incompatibility between A and B , quantified by the product c{hi} N. We predict 5 stable nanophases: layers, cylinders, 3 D spherical cells, 4D spherical cells, and 5D spherical cells. In the strong segregation limit, that is for large c{hi}N, the order-order transition compositions are determined by the strong segregation theory (SST) in its simplest form. While the predictions of the SST theory are close to the corresponding SCFT extrapolations for d=4, the extrapolations for d=5 significantly differ from them. We find that the S5 nanophase is stable in a narrow strip between the ordered S4 nanophase and the disordered phase. The calculated order-disorder transition lines depend weakly on d, as expected." @default.
- W2065430049 created "2016-06-24" @default.
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- W2065430049 date "2014-10-11" @default.
- W2065430049 modified "2023-09-27" @default.
- W2065430049 title "Phase Diagram of Diblock Copolymer Melt in Dimension d=5" @default.
- W2065430049 hasPublicationYear "2014" @default.
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