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- W2065431452 abstract "Hexafluorobuta-1,3-diene and hexafluorocyclobutene interact with elemental sulphur under conditions of mutual conversion (⩾280 °C) to give the same products, hexafluoro-3,6-dihydro-1,2-dithiine (1), hexafluorothiolene-3 (2) and hexafluorothiolanethione (3). The product composition and ratio depend on the reaction conditions. Dithiine 1 and thiolene 2 were formed in competitive reactions. Their thermal stability and the retrocycloaddition reaction of dithiine 1 have been studied. The latter reaction results in thiolene 2 in addition to the formation of hexafluorocyclobutene. This is consistent with a stepwise mechanism for the retrocycloaddition as well as the cycloaddition reaction." @default.
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- W2065431452 date "1993-12-01" @default.
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- W2065431452 title "Thermal reactions of hexafluorobutadiene and hexafluorocyclobutene with elemental sulphur" @default.
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- W2065431452 doi "https://doi.org/10.1016/s0022-1139(00)80855-6" @default.
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