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- W2065431690 abstract "Polymer-supported glyoxylate.monohydrate (3) and alpha-imino acetates (7) have been readily prepared from chloromethylated resin via two or three steps. The ene reactions of 3 with alkenes were successfully performed in the presence of Yb(OTf)3 (50 mol %) to afford, after cleavage from the polymer support, the corresponding alpha-hydroxycarboxylic acid esters in good yields. The reactions of 7 with silyl enolates, Danishefsky's diene, and alkenes also proceeded smoothly in the presence of Sc(OTf)3 (20 mol %) to give the corresponding alpha-amino acid, pyridone, and tetrahydroquinoline derivatives, respectively, in good yields." @default.
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- W2065431690 date "2001-02-16" @default.
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- W2065431690 title "Polymer-Supported Glyoxylate and α-Imino Acetates. Versatile Reagents for the Synthesis of α-Hydroxycarboxylic Acid and α-Amino Acid Libraries" @default.
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- W2065431690 doi "https://doi.org/10.1021/cc0000850" @default.
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