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- W2065434258 abstract "The crystal structures of Li[Fe(trtda)]·3H 2 O and Na[Fe(eddda)]·5H 2 O (trtda = trimethylenediaminetetraacetate and eddda = ethylenediamine- N,N′ -diacetate- N,N′ -di-3-propionate) have been determined by single crystal X-ray diffraction techniques. The former crystal was monoclinic with the space group P 2 1 / n , a = 17.775(3), b = 10.261(1), c = 8.883(2)A, β = 95.86(4)° and Z = 4. The latter was also monoclinic with the space group P 2 1 / n , a = 6.894(2), b = 20.710(6), c = 13.966(3)A, β = 101.44(2)° and Z = 4. Both complex anions were found to adopt an octahedral six-coordinated structure with all of six ligand atoms of trdta 4− or eddda 4− coordinated to the Fe(III) ion, unlike the corresponding edta 4− complex which is usually seven-coordinate with the seventh coordination site occupied by H 2 O. Of the three geometrical isomers possible for the eddda complex, the trans (O 5 ) isomer was actually found in the latter crystal. Factors determining the structural types of metal–edta complexes are discussed in detail." @default.
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- W2065434258 title "The crystal and molecular structures of lithium trimethylenediaminetetraacetatoferrate(III) trihydrate Li[Fe(trdta)]·3H2O and sodium ethylenediamine-N,N′-diacetato-N,N′-di-3-propionatoferrate(II) pentahydrate Na[Fe(eddda)]·5H2O" @default.
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- W2065434258 doi "https://doi.org/10.1016/s0020-1693(00)90606-6" @default.
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