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- W2065458885 endingPage "11048" @default.
- W2065458885 startingPage "11040" @default.
- W2065458885 abstract "A series of organically templated vanadium selenites have been prepared under mild hydrothermal conditions. Single crystals were grown from mixtures of VOSO(4), SeO(2), and either 1,4-dimethylpiperazine, 2,5-dimethylpiperazine, or 2-methylpiperazine in H(2)O. Each compound contains one-dimensional [VO(SeO(3))(HSeO(3))](n)(n-) secondary building units, which connect to form three-dimensional frameworks in the presence of 2,5-dimethylpiperazine or 2-methylpiperazine. Differences in composition and both intra-secondary building unit and organic-inorganic hydrogen-bonding between compounds dictate the dimensionality of the resulting inorganic structures. [1,4-dimethylpiperazineH(2)][VO(SeO(3))(HSeO(3))](2) contains one-dimensional [VO(SeO(3))(HSeO(3))](n)(n-) chains, while [2,5-dimethylpiperazineH(2)][VO(SeO(3))(HSeO(3))](2)·2H(2)O contains a three-dimensional [VO(SeO(3))(HSeO(3))](n)(n-) framework. The use of racemic 2-methylpiperazine also results in a compound containing a three-dimensional [VO(SeO(3))(HSeO(3))](n)(n-) framework, crystallizing in the noncentrosymmetric polar, achiral space group Pca2(1) (no. 29), while analogous reactions containing either (R)-2-methylpiperazine or (S)-2-methylpiperazine result in noncentrosymmetric, nonpolar chiral frameworks that crystallize in P2(1)2(1)2 (no. 18). The formation of these noncentrosymmetric framework materials is dictated by the structure, symmetry, and hydrogen-bonding properties of the [2-methylpiperazineH(2)](2+) cations." @default.
- W2065458885 created "2016-06-24" @default.
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- W2065458885 date "2012-09-24" @default.
- W2065458885 modified "2023-10-14" @default.
- W2065458885 title "Role of Hydrogen-Bonding in the Formation of Polar Achiral and Nonpolar Chiral Vanadium Selenite Frameworks" @default.
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- W2065458885 doi "https://doi.org/10.1021/ic3015496" @default.
- W2065458885 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23003324" @default.
- W2065458885 hasPublicationYear "2012" @default.
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