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• W2065485526 abstract "Ion-selective electrodes based on the bifunctional chelating agent O-methyldihexylphosphine oxide O'-hexyl-2-ethylphosphoric acid (HL) incorporated into a poly(vinyl chloride) membrane were developed. This new derivative is proposed as a single molecular unit combining the overall properties of the synergistic single components, di-2-ethylhexylphosphoric acid and trioctylphosphine oxide. Two different ionophores, HL and its uranyl complex (UO2L2), were studied. The response of the electrodes to uranyl ion was Nernstian for UO2L2 and super-Nernstian for HL ionophores, with detection limits of 3.0 x 10(-6) and 2.0 x 10(-5) M, respectively. Results indicate a more effective interaction with the analyte in the case of having a unique molecule incorporating the two functional groups immobilized into a polymeric membrane, rather than the separated two synergistic ligands. Flow-through tubular electrodes based on both ionophores were also used as potentiometric detectors in flow injection techniques." @default.
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• W2065485526 date "2000-03-07" @default.
• W2065485526 modified "2023-10-03" @default.
• W2065485526 title "Uranyl-Selective Electrode Based on a New Bifunctional Derivative Combining the Synergistic Properties of Phosphine Oxide and Ester of Phosphoric Acid" @default.
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• W2065485526 doi "https://doi.org/10.1021/ac990806l" @default.
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