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- W2065488569 abstract "The formation of bicyclic amines by the intramolecular cyclization of 4-aza-6-methoxycarbonyl-5-hexenyl radicals is described. The direct attachment of a nitrogen atom to the double bond changes the electronic nature of the alkene such that the cyclization is less efficient than the all carbon analogue or the other aza-substituted 5-hexenyl cyclizations.The reaction has been used in a short, convenient synthesis of a variety of indolizidines from methyl nicotinate. In addition, the cyclization was used as the key step in a short synthesis of (±)-epilupinine from methyl nicotinate." @default.
- W2065488569 created "2016-06-24" @default.
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- W2065488569 date "1989-01-01" @default.
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- W2065488569 title "The synthesis of indolizidine and quinolizidine ring systems by free radical cyclization of 4-aza-6-methoxycarbonyl-5-hexenyl radicals" @default.
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- W2065488569 doi "https://doi.org/10.1016/s0040-4020(01)81101-7" @default.
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