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- W2065495924 abstract "The pure rotational spectrum of the vanadium sulfide radical, VS (X4Σ−), has been measured in the frequency range 5–310 GHz using a combination of millimeter-wave direct absorption and Fourier transform microwave (FTMW) techniques. In the millimeter-wave region, the radical was produced in an AC discharge from the reaction of VCl4, the vanadium donor, and CS2. In the FTMW instrument, the molecule was created in a supersonic jet, coupled with a laser ablation/DC discharge source (DALAS), from a mixture of metal vapor and H2S, heavily diluted in argon. A total of 8 rotational transitions were measured for VS, in which both the quartet fine structure and vanadium hyperfine splittings were resolved. The spectra were analyzed with a Hund’s case (b) Hamiltonian, and rotational, spin–rotation, spin–spin, and hyperfine parameters were determined. The precision of the constants from previous optical studies was refined and, for the first time, the vanadium quadrupole constant, eQq = −7.6 (4.0) MHz, and the third order Fermi contact correction, bS = −0.293 (94) MHz, were established. From the fine structure parameters, the nearby 4Π and 2Σ+ states were estimated to lie ∼6560 cm−1 and ∼7170 cm−1 above the ground state. The hyperfine constants suggest that the bonding in VS is partly ionic, with a significant degree of covalent character." @default.
- W2065495924 created "2016-06-24" @default.
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- W2065495924 date "2013-08-01" @default.
- W2065495924 modified "2023-09-24" @default.
- W2065495924 title "The pure rotational spectrum of VS (X4Σ−): A combined Fourier transform microwave and millimeter-wave study" @default.
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- W2065495924 doi "https://doi.org/10.1016/j.jms.2013.07.002" @default.
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