FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2065497035> ?p ?o ?g. }

• W2065497035 endingPage "330" @default.
• W2065497035 startingPage "325" @default.
• W2065497035 abstract "Abstract Sensitized photooxidation of a model 1,4‐diene, 4 cis , 7 cis ‐undecadiene, was shown to yield 4‐hydroperoxy‐5 trans ,7 cis ‐undecadiene and 5‐hydroperoxy‐3 trans ,7 cis ‐undecadiene as initial products. Further irradiation (in the presence of the sensitizer) caused the isomerization of 4‐hydroperoxy‐5 trans ,7 cis ‐undecadiene to 4‐hydroperoxy‐5 trans ,7 trans ‐undecadiene. Oxidation of 4 cis ,7 cis ‐undecadiene with chemically formed singlet oxygen gave the same initial products as the photosensitized oxidation. 5‐Hydroperoxy‐3 trans ,7 cis ‐undecadiene is, however, not formed in the radical autoxidation of the diene. It is concluded that singlet oxygen is the reactive intermediate in the photooxidation. Comparison with this model reaction suggests that the photooxidation of refined soybean oil in propanol also proceeds via singlet oxygen: the photooxidations of both 4,7‐undecadiene and soybean oil are inhibited by β‐carotene and by triethylamine, but unlike radical chain autoxidation, they are not inhibited by 2,6‐di‐ t ‐butyl‐4‐methylphenol. Also soybean oil can act as a sensitizer for the photooxidation of 4,7‐undecadiene. Chlorophyl‐like sensitizers are probably unimportant in the well refined soybean oil used in this work. The observed photooxidation of the skipped dienoic components of soybean oil, which is probably due to some other, unidentified sensitizer(s), absorbing below 500 nm, can be avoided by using a yellow filter." @default.
• W2065497035 created "2016-06-24" @default.
• W2065497035 creator A5012461380 @default.
• W2065497035 creator A5026556868 @default.
• W2065497035 creator A5037741011 @default.
• W2065497035 creator A5042746136 @default.
• W2065497035 creator A5066021851 @default.
• W2065497035 date "1973-08-01" @default.
• W2065497035 modified "2023-10-06" @default.
• W2065497035 title "Participation of singlet oxygen in photosensitized oxidation of 1,4‐dienoic systems and photooxidation of soybean oil" @default.
• W2065497035 cites W1976196863 @default.
• W2065497035 cites W1979098727 @default.
• W2065497035 cites W1988219437 @default.
• W2065497035 cites W1993122113 @default.
• W2065497035 cites W1996371514 @default.
• W2065497035 cites W2006251774 @default.
• W2065497035 cites W2010811962 @default.
• W2065497035 cites W2015768512 @default.
• W2065497035 cites W2022189908 @default.
• W2065497035 cites W2033448385 @default.
• W2065497035 cites W2039480072 @default.
• W2065497035 cites W2055266482 @default.
• W2065497035 cites W2062519842 @default.
• W2065497035 cites W2066515169 @default.
• W2065497035 cites W2079657050 @default.
• W2065497035 cites W2081309606 @default.
• W2065497035 cites W2103048137 @default.
• W2065497035 cites W2141919881 @default.
• W2065497035 cites W2160414582 @default.
• W2065497035 cites W2315026187 @default.
• W2065497035 cites W4252733623 @default.
• W2065497035 doi "https://doi.org/10.1007/bf02641366" @default.
• W2065497035 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/4799002" @default.
• W2065497035 hasPublicationYear "1973" @default.
• W2065497035 type Work @default.
• W2065497035 sameAs 2065497035 @default.
• W2065497035 citedByCount "71" @default.
• W2065497035 countsByYear W20654970352012 @default.
• W2065497035 countsByYear W20654970352014 @default.
• W2065497035 countsByYear W20654970352015 @default.
• W2065497035 countsByYear W20654970352017 @default.
• W2065497035 countsByYear W20654970352019 @default.
• W2065497035 crossrefType "journal-article" @default.
• W2065497035 hasAuthorship W2065497035A5012461380 @default.
• W2065497035 hasAuthorship W2065497035A5026556868 @default.
• W2065497035 hasAuthorship W2065497035A5037741011 @default.
• W2065497035 hasAuthorship W2065497035A5042746136 @default.
• W2065497035 hasAuthorship W2065497035A5066021851 @default.
• W2065497035 hasConcept C121332964 @default.
• W2065497035 hasConcept C126661725 @default.
• W2065497035 hasConcept C161790260 @default.
• W2065497035 hasConcept C176933379 @default.
• W2065497035 hasConcept C178790620 @default.
• W2065497035 hasConcept C181500209 @default.
• W2065497035 hasConcept C185544564 @default.
• W2065497035 hasConcept C185592680 @default.
• W2065497035 hasConcept C2777516457 @default.
• W2065497035 hasConcept C2778733088 @default.
• W2065497035 hasConcept C2779885280 @default.
• W2065497035 hasConcept C31903555 @default.
• W2065497035 hasConcept C33062035 @default.
• W2065497035 hasConcept C37329643 @default.
• W2065497035 hasConcept C540031477 @default.
• W2065497035 hasConcept C75473681 @default.
• W2065497035 hasConceptScore W2065497035C121332964 @default.
• W2065497035 hasConceptScore W2065497035C126661725 @default.
• W2065497035 hasConceptScore W2065497035C161790260 @default.
• W2065497035 hasConceptScore W2065497035C176933379 @default.
• W2065497035 hasConceptScore W2065497035C178790620 @default.
• W2065497035 hasConceptScore W2065497035C181500209 @default.
• W2065497035 hasConceptScore W2065497035C185544564 @default.
• W2065497035 hasConceptScore W2065497035C185592680 @default.
• W2065497035 hasConceptScore W2065497035C2777516457 @default.
• W2065497035 hasConceptScore W2065497035C2778733088 @default.
• W2065497035 hasConceptScore W2065497035C2779885280 @default.
• W2065497035 hasConceptScore W2065497035C31903555 @default.
• W2065497035 hasConceptScore W2065497035C33062035 @default.
• W2065497035 hasConceptScore W2065497035C37329643 @default.
• W2065497035 hasConceptScore W2065497035C540031477 @default.
• W2065497035 hasConceptScore W2065497035C75473681 @default.
• W2065497035 hasIssue "8" @default.
• W2065497035 hasLocation W20654970351 @default.
• W2065497035 hasLocation W20654970352 @default.
• W2065497035 hasOpenAccess W2065497035 @default.
• W2065497035 hasPrimaryLocation W20654970351 @default.
• W2065497035 hasRelatedWork W1979098727 @default.
• W2065497035 hasRelatedWork W1988722534 @default.
• W2065497035 hasRelatedWork W2011591073 @default.
• W2065497035 hasRelatedWork W2032895273 @default.
• W2065497035 hasRelatedWork W2062551404 @default.
• W2065497035 hasRelatedWork W2065497035 @default.
• W2065497035 hasRelatedWork W2089272666 @default.
• W2065497035 hasRelatedWork W2355483408 @default.
• W2065497035 hasRelatedWork W4251754090 @default.
• W2065497035 hasRelatedWork W4382726527 @default.
• W2065497035 hasVolume "50" @default.
• W2065497035 isParatext "false" @default.
• W2065497035 isRetracted "false" @default.

• next