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- W2065500353 abstract "Stereoselectivity in the reduction of substituted cyclohexanones, 4-tert-butylcycohexanone, 2-methylcycohexanone, 2-phenylcyclohexanone, and 2-methoxycarbonyl-methylcyclohexanone, was examined with chiral rhodium-bis(oxazolinyl)pyridine catalyst and diphenylsilane. 4-tert-Butylcyclohexanone gave the corresponding trans(equatorial)-alcohol predominantly; the ratio of the trans/cis alcohols, 67:33. Other 2-substituted cyclohexanones showed exclusive enantioselectivities for each diastereomer in terms of the kinetic resolution; e.g. from 2-phenylcyclohexanone, 99 % ee of (1S, 2R)-trans-2-phenylcyclohexanol and 96 % ee of (1S, 2S)-cis-2-phenylcyclohexanol in 92 % yield (the trans/cis ratio = 51:49)." @default.
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- W2065500353 date "1992-08-01" @default.
- W2065500353 modified "2023-10-09" @default.
- W2065500353 title "Stereoselectivity in hydrosilylative reduction of substituted cyclohexanone derivatives with chiral rhodium-bis(oxazolinyl)pyridine catalyst" @default.
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- W2065500353 doi "https://doi.org/10.1016/s0957-4166(00)86036-x" @default.
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