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- W2065571851 abstract "Solvent effects on the binary mixtures of amides with alcohols and water were investigated by means of Reichardt's ET(30) solvatochromic indicator. E parameters of binary solvent mixtures of formamide, N-methylformamide and N,N-dimethylformamide with water, methanol, propan-2-ol, 2-methylpropan-2-ol, formamide, N-methylformamide and N,N-dimethylformamide were measured over the whole composition range of the mixtures. Application of a preferential solvation model to the solvatochromic data shows that the preferential solvation of the solvatochromic indicator by the amides decreases in the order N-methylformamide > formamide > N,N-dimethylformamide. Synergism is observed for the mixtures of the amides with alcohols of similar polarity (E value), i.e. methanol–formamide, methanol–N-methylformamide, propan-2-ol–N,N-dimethylformamide and 2-methylpropan-2-ol–N,N-dimethylformamide binary systems. Copyright © 1999 John Wiley & Sons, Ltd." @default.
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- W2065571851 date "1999-02-01" @default.
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- W2065571851 title "Solute-solvent and solvent-solvent interactions in binary solvent mixtures. Part 8. TheET(30) polarity of binary mixtures of formamides with hydroxylic solvents" @default.
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- W2065571851 doi "https://doi.org/10.1002/(sici)1099-1395(199902)12:2<109::aid-poc97>3.0.co;2-l" @default.
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