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- W2065578497 abstract "Certain types of unsaturated lactones exhibit two bands in the region of the spectrum associated with the C=O stretching vibrational mode. This is observed both in the infrared and Raman spectra.The infrared spectra of 23 simple saturated and unsaturated lactones have been examined in an attempt to determine the structural features with which this carbonyl band splitting is associated. It appears to be common to most unsaturated five- and six-membered ring lactones in which the double bond is conjugated with the carbonyl group, though one well-established exception has been observed. The relative intensities of the two bands are extremely sensitive to changes in the polarity of the solvent; they also vary reversibly with temperature but are independent of concentration.The splitting of the C=O stretching band is attributed to an intramolecular vibrational effect similar to that which occurs in cyclopentanone and in certain Δ 2 -cyclopentenone derivatives. Its possible dependence on Fermi resonance with the overtone of a lower lying fundamental vibration is discussed.Similar effects occur in other types of carbonyl compounds, such as benzoyl chloride and cyclic five-membered ring anhydrides, and care is needed to distinguish carbonyl band splitting of this kind from that associated with equilibria between conformational isomers." @default.
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- W2065578497 date "1959-12-01" @default.
- W2065578497 modified "2023-09-25" @default.
- W2065578497 title "THE CARBONYL STRETCHING BANDS IN THE INFRARED SPECTRA OF UNSATURATED LACTONES" @default.
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- W2065578497 doi "https://doi.org/10.1139/v59-293" @default.
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