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- W2065631231 abstract "An apparatus suitable to measure 13C relaxation times T1 and T2 in liquids at 62 MHz is described. The required field of 58 kG is generated by a superconducting magnet. Results of T1 measurements on a variety of liquids, including benzene, derivatives of benzene, saturated rings, CS2, and others are reported. They are discussed in terms of dipole--dipole interactions, spin-rotation interactions and anisotropic chemical shifts, the latter of which turn out to play only a minor role. Intramolecular dipole-dipole interactions are found to provide by far the most important spin-lattice relaxation mechanism, whenever protons are bound directly to the carbons under investigation, even when the samples contain dissolved oxygen." @default.
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- W2065631231 date "1971-04-01" @default.
- W2065631231 modified "2023-10-06" @default.
- W2065631231 title "13C nuclear magnetic relaxation studies at 62 MHz" @default.
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- W2065631231 doi "https://doi.org/10.1016/0022-2364(71)90104-1" @default.
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