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- W2065633998 abstract "The exact knowledge of the thermodynamic and the kinetic properties of a chemical reaction allows the prediction of the safe and dangerous states of this reaction under technical conditions. Reaction calorimetric measurements of the polymerisation reaction of propylene oxide on polyfunctional alcohols showed that this reaction can be described by a modified first-order kinetic equation and that it releases a reaction energy of 1358 ± 99 kJ per kg propylene oxide. With fixed thermodynamic and kinetic data, technical and operational failures were simulated. This led to a concept for the safe handling of the polymerisation. The concept establishes a limit curve in temperature and pressure. During the dosing of the propylene oxide, the measured temperature and pressure values have to be below this limit, otherwise the design pressure of the production reactor will be exceeded resulting in an adiabatic runaway reaction." @default.
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- W2065633998 date "1993-10-01" @default.
- W2065633998 modified "2023-09-25" @default.
- W2065633998 title "Safety assessment for polyetherol production using reaction kinetic data" @default.
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- W2065633998 doi "https://doi.org/10.1016/0040-6031(93)80187-f" @default.
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