Matches in SemOpenAlex for { <https://semopenalex.org/work/W2065643756> ?p ?o ?g. }
- W2065643756 endingPage "1479" @default.
- W2065643756 startingPage "1474" @default.
- W2065643756 abstract "Samples of mesoporous silica SBA-15 with and without controlled framework microporosity were prepared under microwave hydrothermal conditions. These samples were evaluated for their ability to separate ethane and ethylene by obtaining their equilibrium adsorption isotherms using volumetric adsorption at 303 and 323 K, respectively. The data obtained were analyzed using the Langmuir−Freundlich adsorption isotherm model. Although the mesoporous silica samples showed a higher adsorption capacity for ethylene, it was found to decrease upon reduction in the adsorbent's framework microporosity. Likewise, the isosteric heats of adsorption estimated by the Clausius−Clapeyron equation are higher for ethylene as compared to those for ethane and were also found to depend on framework microporosity. The sample with higher microporosity displayed strong affinity for ethylene and is comparable with those reported for π-complexation-based systems. This affinity was observed to weaken on the sample with lower microporosity and absent altogether on the micropore-free SBA-15 sample. Furthermore, the affinity of the micropore-free SBA-15 framework for ethylene and ethane was observed to be similar to and comparable with those obtained on MCM-41 type mesoporous silica. The thus-obtained trend has revealed the importance of framework microporosity in designing a SBA-15-based adsorbent for ethane/ethylene separation." @default.
- W2065643756 created "2016-06-24" @default.
- W2065643756 creator A5003059320 @default.
- W2065643756 creator A5043894955 @default.
- W2065643756 creator A5064895755 @default.
- W2065643756 creator A5070987880 @default.
- W2065643756 creator A5072184244 @default.
- W2065643756 creator A5073748167 @default.
- W2065643756 creator A5079100428 @default.
- W2065643756 date "2003-03-07" @default.
- W2065643756 modified "2023-09-23" @default.
- W2065643756 title "Potential Adsorbent for Light Hydrocarbon Separation: Role of SBA-15 Framework Porosity" @default.
- W2065643756 cites W1613744352 @default.
- W2065643756 cites W1964268010 @default.
- W2065643756 cites W1964379883 @default.
- W2065643756 cites W1967949553 @default.
- W2065643756 cites W1970838735 @default.
- W2065643756 cites W1978254867 @default.
- W2065643756 cites W1980379757 @default.
- W2065643756 cites W1983486029 @default.
- W2065643756 cites W1986361781 @default.
- W2065643756 cites W1986818240 @default.
- W2065643756 cites W1987388741 @default.
- W2065643756 cites W1988745485 @default.
- W2065643756 cites W1989158191 @default.
- W2065643756 cites W1993890175 @default.
- W2065643756 cites W1994582943 @default.
- W2065643756 cites W1995041236 @default.
- W2065643756 cites W2006939298 @default.
- W2065643756 cites W2008244335 @default.
- W2065643756 cites W2011964856 @default.
- W2065643756 cites W2021989193 @default.
- W2065643756 cites W2022415942 @default.
- W2065643756 cites W2033779864 @default.
- W2065643756 cites W2034190603 @default.
- W2065643756 cites W2034830770 @default.
- W2065643756 cites W2039241045 @default.
- W2065643756 cites W2039855563 @default.
- W2065643756 cites W2046430541 @default.
- W2065643756 cites W2046468736 @default.
- W2065643756 cites W2061425502 @default.
- W2065643756 cites W2070662104 @default.
- W2065643756 cites W2087573918 @default.
- W2065643756 cites W2110249624 @default.
- W2065643756 cites W2110561233 @default.
- W2065643756 cites W2140362427 @default.
- W2065643756 cites W2160150335 @default.
- W2065643756 cites W2171631314 @default.
- W2065643756 cites W2952894067 @default.
- W2065643756 doi "https://doi.org/10.1021/cm020889d" @default.
- W2065643756 hasPublicationYear "2003" @default.
- W2065643756 type Work @default.
- W2065643756 sameAs 2065643756 @default.
- W2065643756 citedByCount "83" @default.
- W2065643756 countsByYear W20656437562012 @default.
- W2065643756 countsByYear W20656437562013 @default.
- W2065643756 countsByYear W20656437562014 @default.
- W2065643756 countsByYear W20656437562015 @default.
- W2065643756 countsByYear W20656437562016 @default.
- W2065643756 countsByYear W20656437562017 @default.
- W2065643756 countsByYear W20656437562018 @default.
- W2065643756 countsByYear W20656437562019 @default.
- W2065643756 countsByYear W20656437562020 @default.
- W2065643756 countsByYear W20656437562021 @default.
- W2065643756 countsByYear W20656437562022 @default.
- W2065643756 crossrefType "journal-article" @default.
- W2065643756 hasAuthorship W2065643756A5003059320 @default.
- W2065643756 hasAuthorship W2065643756A5043894955 @default.
- W2065643756 hasAuthorship W2065643756A5064895755 @default.
- W2065643756 hasAuthorship W2065643756A5070987880 @default.
- W2065643756 hasAuthorship W2065643756A5072184244 @default.
- W2065643756 hasAuthorship W2065643756A5073748167 @default.
- W2065643756 hasAuthorship W2065643756A5079100428 @default.
- W2065643756 hasConcept C112825004 @default.
- W2065643756 hasConcept C115958267 @default.
- W2065643756 hasConcept C127413603 @default.
- W2065643756 hasConcept C150394285 @default.
- W2065643756 hasConcept C156622251 @default.
- W2065643756 hasConcept C161790260 @default.
- W2065643756 hasConcept C178790620 @default.
- W2065643756 hasConcept C185592680 @default.
- W2065643756 hasConcept C192562407 @default.
- W2065643756 hasConcept C2777207669 @default.
- W2065643756 hasConcept C2777496208 @default.
- W2065643756 hasConcept C2778597550 @default.
- W2065643756 hasConcept C42360764 @default.
- W2065643756 hasConcept C43617362 @default.
- W2065643756 hasConcept C6648577 @default.
- W2065643756 hasConcept C82776694 @default.
- W2065643756 hasConcept C86381522 @default.
- W2065643756 hasConceptScore W2065643756C112825004 @default.
- W2065643756 hasConceptScore W2065643756C115958267 @default.
- W2065643756 hasConceptScore W2065643756C127413603 @default.
- W2065643756 hasConceptScore W2065643756C150394285 @default.
- W2065643756 hasConceptScore W2065643756C156622251 @default.
- W2065643756 hasConceptScore W2065643756C161790260 @default.
- W2065643756 hasConceptScore W2065643756C178790620 @default.
- W2065643756 hasConceptScore W2065643756C185592680 @default.