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• W2065647920 abstract "The ability of [(η5Me5C5)M(L)Cl]+ (L = 2,2−bipyridine ligands; M = Rh(III) and Ir(III) to act as an electrocatalyst for CO2 reduction has been examined in an aqueous organic medium. It appears that the Rh(III) complex is a better catalyst than the Ir(III) one, and that a current efficiency for formate production of up to 50% can be reached. The initial step of the electrocatalysis involves the formation of the corresponding hydrido complex. Immobilization of such catalysts on the electrode surface, by the technique of functionalized polypyrrole films, decreases their efficiency as a consequence of the lower efficiency of the insertion of CO2 into the metal-hydride bond." @default.
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• W2065647920 date "1997-08-01" @default.
• W2065647920 modified "2023-10-18" @default.
• W2065647920 title "Electrocatalytic reduction of CO2 into formate with [(η5Me5C5)M(L)Cl]+ complexes (L = 2,2′-bipyridine ligands; M  Rh(III) and Ir(III))" @default.
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• W2065647920 doi "https://doi.org/10.1016/s0022-0728(97)00058-2" @default.
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