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- W2065648489 abstract "The reaction of electrochemically generated Mmnt3−2 (M = Rh, Co, Ni) complexes with weak protonic acids was studied using various electrochemically techniques. Complexes with M = Rh and Co react under the formation of a protonated species from which hydrogen is evolved at a dropping mercury electrode at potentials more negative than are those of the Mmnt2−2/Mmnt3−2 couple. Comparison with the behaviour of other protonated transition metal complexes led to the conclusion that the protonation site in Mmnt3−2 units is the metal atom. Protonation of Rhmnt3−3, prepared by reduction with LiAlH4, was studied spectrophotometrically in solution. [Rh(H)mnt2]2− gives a characteristic band at 464 nm. Reduction of the latter species leads to Rhmnt3−2 whereas oxidation results in Rhmnt2−2. [Rh(H)mnt2]2− decomposes slowly in solution under the formation of Rhmnt2−2 and hydrogen evolution; the stability of the corresponding Co-species is considerably smaller. Nimnt3−2 is oxidized rapidly by the weak acids used to give Nimnt2−2." @default.
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- W2065648489 date "1980-01-01" @default.
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- W2065648489 title "Metal-localized protonation of Mmnt3−2 (M = Rh, Co) complexes" @default.
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- W2065648489 doi "https://doi.org/10.1016/s0020-1693(00)88441-8" @default.
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