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• W2065650183 endingPage "2529" @default.
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• W2065650183 abstract "The use of the substituted benzotriazole ligand btaOH (1-hydroxybenzotriazole) in copper(II) chemistry has yielded a structurally and magnetically very interesting complex. The [Cu2(O2CMe)4(H2O)2]/btaOH.H2O/aqueous NH3 (1:4:4, 1:3:3, 1:2:2) reaction system in MeOH gives dark brown-green [Cu(btaO)2(MeOH)]n (4) in approximately 80% yield. 4 crystallizes in the tetragonal space group P4(3)2(1)2 with (at 25 degrees C) a = 9.915(1) A, b = 9.915(1) A, c = 14.715(2) A, and Z = 4. The structure consists of a 3D, diamond-like copper(II) lattice. The CuII atom has a square pyramidal geometry with four btaO- ligands at the basal plane. The btaO- ion functions as a bidentate bridging ligand, with N(3) and the deprotonated oxygen being the ligating atoms. Dc and ac magnetic susceptibility measurements, together with low-field (10 G) and high-field (up to 5000 G) magnetization data, are consistent with ferromagnetic interactions on the scale of the crystal lattice with two critical temperatures: 6.4 and 4.4 K. The former critical temperature could correspond to a transition from a paramagnetic to a ferromagnetic state; the latter one, to a transition from a ferromagnetically ordered state to its 3D ordering. The magnetic data, along with the field dependence of the magnetization and the EPR data, are also in line with a soft magnet. Moreover, the EPR studies performed on 4 reveal unique features reported for the first time in the field of molecular magnetism." @default.
• W2065650183 created "2016-06-24" @default.
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• W2065650183 date "2000-05-23" @default.
• W2065650183 modified "2023-10-03" @default.
• W2065650183 title "Ferromagnetism in an Extended Three-Dimensional, Diamond-like Copper(II) Network: A New Copper(II)/1-Hydroxybenzotriazolato Complex Exhibiting Soft-Magnet Properties and Two Transitions at 6.4 and 4.4 K" @default.
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• W2065650183 doi "https://doi.org/10.1021/ic991149i" @default.
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