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- W2065651036 abstract "The 29Si- and 13C-NMR spectral parameters of a range of N-(amidomethyl)-polyhalosilanes have been measured in solution and the extent of SiO bond formation and pentacoordination determined. The larger the number of electronegative groups attached to the silicon the greater the extent of pentacoordination achievable by the silicon. Thus with trichlorosilanes a ‘tight’ pentacoordinate silicon is observed where the SiO bond is almost fully formed." @default.
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- W2065651036 date "2000-07-01" @default.
- W2065651036 modified "2023-09-27" @default.
- W2065651036 title "Modelling nucleophilic substitution at silicon using hypervalent silicon compounds based on di and tri halosilanes" @default.
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- W2065651036 doi "https://doi.org/10.1016/s0022-328x(00)00263-1" @default.
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