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- W2065652245 abstract "Abstract Unlike common oxovanadium(IV) complexes with tetradentate Schiff base ligands, [N,N′-(2,2-dimethyl-1,3-propylene)bis(salicylideneiminato)]oxovanadium(IV) ([VO(salptn)]) was easily oxidized by dioxygen in aqueous CH3CN. The [VO(salptn)]–O2 stoichiometry was 4:1. This particular reactivity comes from the preference of [VO(salptn)] to be six-coordinate rather than five, that drives the formation of an O2-complex. The structure of the oxidized product, [VO(salptn)]OH, was characterized by single-crystal X-ray diffraction. The results are consistent with a mechanism involving an attack of O2 at the vanadium(IV) center, followed by the formation of the μ-dioxo dimmer as a transient species and the subsequent splitting of the O–O bond by hydrolysis to yield [VO(salptn)]OH." @default.
- W2065652245 created "2016-06-24" @default.
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- W2065652245 date "2003-09-01" @default.
- W2065652245 modified "2023-10-14" @default.
- W2065652245 title "Oxovanadium(V) hydroxide with a tetradentate Schiff base ligand resulting from oxidation of oxovanadium(IV) with O2" @default.
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- W2065652245 doi "https://doi.org/10.1016/s0020-1693(03)00310-4" @default.
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