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- W2065653721 endingPage "3208" @default.
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- W2065653721 abstract "The thiocyanatoaqua-tris(1,10-phenanthroline)lanthanide(III)thiocyanates, [Ln(phen)3(H2O)(SCN)](SCN)2 (where Ln = LaIII and all trivalent lanthanides, except Pm and Lu) have been synthesized and characterized. The molar conductances, IR spectra and thermograms show the presence of both coordinated and non-coordinated thiocyanate. The complexes are eight-coordinate. Very large chemical shifts are observed in the NMR spectra of paramagnetic complexes. The interelectronic and covalency parameters calculated for the complexes show the covalent nature of bonding between the metal and the ligand. The oscillator strengths of the f-f transitions are calculated and discussed. The complexes appear to accept one solvent molecule (DMSO) and become nine-coordinate in solution." @default.
- W2065653721 created "2016-06-24" @default.
- W2065653721 creator A5063630197 @default.
- W2065653721 creator A5073655947 @default.
- W2065653721 date "1994-12-01" @default.
- W2065653721 modified "2023-09-24" @default.
- W2065653721 title "Mixed-ligand lanthanide complexes—VII. Complexes of 1,10-phenanthroline and thiocyanate" @default.
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- W2065653721 doi "https://doi.org/10.1016/s0277-5387(00)83382-3" @default.
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