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• W2065654015 startingPage "2477" @default.
• W2065654015 abstract "Abstract A new Schiff‐base ligand having a potentially coordinating thioether group (2‐quinoline‐ N ‐(2′‐methylthiophenyl)methyleneimine, qmtpm ) has been prepared. The synthesis, structure, UV‐Vis and EPR studies of one copper(II) and two cobalt(II) complexes from this ligand is reported. The X‐ray structures of the Cu II and Co II chlorido complexes 1 and 2 reveal the metal atoms in highly distorted square‐pyramidal environments constituted of one tridentate ligand and two anions. On the other hand, the thiocyanato Co II compound 3 exhibits a distorted trigonal‐bipyramidal structure. These structural variations are apparently due to the different counter‐ions which leads to distinct lattice interactions. The spectroscopic data obtained by EPR and UV‐Vis investigations are in agreement with the solid‐state structures of the coordination compounds." @default.
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• W2065654015 date "2008-10-27" @default.
• W2065654015 modified "2023-10-08" @default.
• W2065654015 title "A New Sulfur-containing Schiff-Base Ligand and Binding to Copper(II) and Cobalt(II)" @default.
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• W2065654015 doi "https://doi.org/10.1002/zaac.200800360" @default.
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