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- W2065684913 abstract "Marongiu, B., Monaci, R. and Porcedda, S., 1993. Excess Gibbs energies and excess enthalpies of liquid binary mixtures containing nitroalkanes. Fluid Phase Equilibria, 84:281-296. A head-space gas Chromatographie technique was used to determine vapour phase equilibria for binary mixtures of 1-nitroalkanes (1-nitropropane, 1-nitrobutane, 1-nitropentane) + n-heptane or cyclohexane. Excess molar Gibbs energies, GE, for the mixtures investigated were obtained. All systems exhibit positive deviations. The GE values decrease with increasing nitroalkane chain length. Activity coefficients at infinite dilution, γ∞t, were also evaluated. A flow microcalorimeter, Model 2277-LK.B, was used to determine excess enthalpies, HE, as a function of concentration at atmospheric pressure and 298.15 K, for binary liquid mixtures containing the same 1-nitroalkanes with tetrachloromethane. A tentative approach, based on an additivity scheme of surface interactions combined with the scaled particle theory, is presented to estimate and analyse group contributions to ΔGsolv0 and ΔHsolv0, the energy and the enthalpy of solvation respectively." @default.
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- W2065684913 date "1993-04-01" @default.
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- W2065684913 title "Excess Gibbs energies and excess enthalpies of liquid binary mixtures containing nitroalkanes" @default.
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- W2065684913 doi "https://doi.org/10.1016/0378-3812(93)85128-9" @default.
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