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- W2065689312 abstract "The imino 1,2-Wittig rearrangement of hydroximates provides a novel method for the construction of 2-hydroxyoxime ethers. Upon treatment with LDA, Z-hydroximates smoothly underwent stereoselective rearrangement to give Z-2-hydroxyoxime ethers in good yield, which were converted into amino alcohols. On the other hand, the rearrangement of E-hydroximates gave a mixture of E- and Z-2-hydroxyoxime ethers. This method was successfully applied to a practical synthesis of cytoxazone." @default.
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- W2065689312 date "2004-04-01" @default.
- W2065689312 modified "2023-09-24" @default.
- W2065689312 title "Imino 1,2-Wittig rearrangement of hydroximates and its application to synthesis of cytoxazone" @default.
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- W2065689312 doi "https://doi.org/10.1016/j.tet.2004.02.048" @default.
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