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- W2065695166 abstract "The polymerization of 1,3,5-hexatriene, 1,3,5-heptatriene, and 2,4,6-octatriene with a variety of catalysts established the trienes as a distinct class of monomers which lead to unique unsaturated polyolefins. Soluble, high molecular weight polymers with predominantly 1,6-enchainment were prepared with a soluble coordination catalyst system; this mode of polymerization resulted in 1,3-dienyl groups in the polymer backbone. A stereospecific 1,6-polyhexatriene, with a novel type of crystallinity based on trans, trans-1,3-diene repeat units, was prepared by low temperature polymerization with a vanadyl trichloride–triisobutylauminum catalyst." @default.
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- W2065695166 date "1964-12-01" @default.
- W2065695166 modified "2023-10-17" @default.
- W2065695166 title "Polymerization of conjugated trienes" @default.
- W2065695166 doi "https://doi.org/10.1002/pol.1964.100021225" @default.
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