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- W2065702198 abstract "The in-beam electron ionization (EI) spectra of quaternary ammonium salts of dextromethorphan and piperidine consist of peaks arising both from thermal degradation products and from the fragmentation of the molecular cation [R4N]+. Mass-analysed ion kinetic energy and ion kinetic energy spectra indicate that several major ions believed to be thermally induced before EI are also produced directly from [R4N]+ fragmentation. However, the contribution of the direct fragmentation of [R4N]+ upon EI is small in comparison to that of the thermal degradation products. This behavior was observed in the conformationally flexible and rigid piperidinium rings studied." @default.
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- W2065702198 date "1984-10-01" @default.
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- W2065702198 title "Gas phase electron ionization fragmentation of dextromethorphan and related quaternary ammonium salts" @default.
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- W2065702198 doi "https://doi.org/10.1002/bms.1200111007" @default.
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