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• W2065738519 endingPage "2774" @default.
• W2065738519 startingPage "2767" @default.
• W2065738519 abstract "Excimer laser fragmentation fluorescence spectroscopy (ELFFS) is an effective technique for monitoring diesel particulate matter in engine exhaust. Measurements were made in the exhaust of a single-cylinder, 4 kW diesel generator with several different air to exhaust dilution ratios. Light from a 193 nm ArF laser photofragments the particles and produces fluorescence from the atomic carbon fragments at 248 nm and from CH (431 nm) and C2 (468 nm) fragments. Interferences from carbon monoxide and carbon dioxide are negligible. The interference from unburned gas-phase hydrocarbons is significant when the engine is not under load, but insignificant when the engine is loaded. The gas-phase hydrocarbons can be removed by a diffusion denuder to eliminate this interference under no-load conditions. The 100-shot (1 s) detection limit for particles in the exhaust is approximately 0.2 ppb volume fraction. The single-shot detection limit of ELFFS is low enough to allow for real-time monitoring of particulate matter from diesel engines, as well as from other combustion systems. ELFFS is sensitive to both the volatile and non-volatile fraction of the particulate matter, and monitoring fluorescence from multiple fragments provides information on the chemical composition of the particles." @default.
• W2065738519 created "2016-06-24" @default.
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• W2065738519 date "2002-01-01" @default.
• W2065738519 modified "2023-09-23" @default.
• W2065738519 title "Characterization of diesel particulate matter with excimer laser fragmentation fluorescence spectroscopy" @default.
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• W2065738519 doi "https://doi.org/10.1016/s1540-7489(02)80337-6" @default.
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