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- W2065761108 abstract "Dipole moments of selenobenzamide, of eight N′-thio (oxo or seleno) acylamidines and of two N′-thioacyliminoethylidenetriphenylphosphoranes in carbon tetrachloride, benzene or dioxane solutions were measured or examined. Calculations of molecular moments for the sp (CS and NC on the same side) and ap conformations and for the canonical structures implied by conjugation were performed according to a recently proposed method. A comparison between the calculated and the experimental values shows that only strong conjugations with significant statistical percentages ps(±) of the 1,5 (or 1,6) zwitterionic forms (X−CN−CN+ or X−CNCCP+ with X O, S or Se) can explain observed moments. The μ differences between compounds are related to ps(±) variations which can give information about the molecular structures and their relationship with reactivities." @default.
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- W2065761108 date "1996-08-01" @default.
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- W2065761108 title "Substituted 1-hetero-3-aza-1,3-butadienes: dipole moments and related structural analysis" @default.
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- W2065761108 doi "https://doi.org/10.1016/0022-2860(96)09247-2" @default.
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