FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2065792998> ?p ?o ?g. }

• W2065792998 endingPage "1252" @default.
• W2065792998 startingPage "1243" @default.
• W2065792998 abstract "The regio- and stereochemistries of photo-Claisen reactions of 1-naphthyl (R)-1-phenylethyl ether ((R)-2), in combination with photo-Fries and photo-Claisen-type reactions of 1-naphthyl (R)-2-phenylpropanoate ((R)-1), have been investigated in n-alkanes of different viscosities and at several temperatures. Analyses of the results provide detailed information about the in-cage motions of the singlet prochiral 1-naphthoxy/1-phenylethyl radical pairs (radical-pair B) that are formed directly from (R)-2 and indirectly from (R)-1 via decarbonylation of singlet chiral 1-naphthoxy/2-phenylpropanoyl radical pairs (radical-pair A). In hexane at 23 °C, the photo-Claisen products from irradiations of (R)-2 retain up to 31% enantiomeric excess (ee), but the ees of the same photoproducts from (R)-1 are near 0%. This disparity is attributed to differences between the initial orientations of the constituent radicals of radical-pair B at the moment of their “birth”. The regio- and stereoselectivities reach plateau values as the solvent viscosity increases, indicating that the relationships between the rates of radical−radical bond formation and either translational or tumbling motions within a solvent cage reach an asymptotic limit. Detailed analyses are presented of the various motions that are in competition within a solvent cage during the very short lifetimes of the radical pairs. The data, in toto, present interesting insights into how radical pairs move during short periods and over short distances when their solvent cages have walls of varying flexibility." @default.
• W2065792998 created "2016-06-24" @default.
• W2065792998 creator A5000561706 @default.
• W2065792998 creator A5037486096 @default.
• W2065792998 date "2005-01-22" @default.
• W2065792998 modified "2023-10-18" @default.
• W2065792998 title "Analyses of In-Cage Singlet Radical-Pair Motions from Irradiations of 1-Naphthyl (<i>R</i>)-1-Phenylethyl Ether and 1-Naphthyl (<i>R</i>)-2-Phenylpropanoate in <i>n</i>-Alkanes" @default.
• W2065792998 cites W1967157495 @default.
• W2065792998 cites W1969976967 @default.
• W2065792998 cites W1973665512 @default.
• W2065792998 cites W1975440121 @default.
• W2065792998 cites W1981041592 @default.
• W2065792998 cites W1990488146 @default.
• W2065792998 cites W2005006050 @default.
• W2065792998 cites W2006947798 @default.
• W2065792998 cites W2025685668 @default.
• W2065792998 cites W2028168007 @default.
• W2065792998 cites W2030841140 @default.
• W2065792998 cites W2038069743 @default.
• W2065792998 cites W2039592297 @default.
• W2065792998 cites W2054932519 @default.
• W2065792998 cites W2058532200 @default.
• W2065792998 cites W2085266415 @default.
• W2065792998 cites W2086884840 @default.
• W2065792998 cites W2099833779 @default.
• W2065792998 cites W2329579569 @default.
• W2065792998 cites W2475884896 @default.
• W2065792998 cites W2949626070 @default.
• W2065792998 cites W2950452297 @default.
• W2065792998 cites W3004566430 @default.
• W2065792998 cites W3004757098 @default.
• W2065792998 cites W3005532117 @default.
• W2065792998 doi "https://doi.org/10.1021/jo048182t" @default.
• W2065792998 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15704957" @default.
• W2065792998 hasPublicationYear "2005" @default.
• W2065792998 type Work @default.
• W2065792998 sameAs 2065792998 @default.
• W2065792998 citedByCount "17" @default.
• W2065792998 countsByYear W20657929982012 @default.
• W2065792998 countsByYear W20657929982013 @default.
• W2065792998 countsByYear W20657929982015 @default.
• W2065792998 countsByYear W20657929982018 @default.
• W2065792998 countsByYear W20657929982019 @default.
• W2065792998 countsByYear W20657929982020 @default.
• W2065792998 countsByYear W20657929982022 @default.
• W2065792998 countsByYear W20657929982023 @default.
• W2065792998 crossrefType "journal-article" @default.
• W2065792998 hasAuthorship W2065792998A5000561706 @default.
• W2065792998 hasAuthorship W2065792998A5037486096 @default.
• W2065792998 hasConcept C121332964 @default.
• W2065792998 hasConcept C139066938 @default.
• W2065792998 hasConcept C155647269 @default.
• W2065792998 hasConcept C178790620 @default.
• W2065792998 hasConcept C181500209 @default.
• W2065792998 hasConcept C185544564 @default.
• W2065792998 hasConcept C185592680 @default.
• W2065792998 hasConcept C2780407432 @default.
• W2065792998 hasConcept C2780471494 @default.
• W2065792998 hasConcept C2780567667 @default.
• W2065792998 hasConcept C33062035 @default.
• W2065792998 hasConcept C71240020 @default.
• W2065792998 hasConcept C75079739 @default.
• W2065792998 hasConcept C75473681 @default.
• W2065792998 hasConceptScore W2065792998C121332964 @default.
• W2065792998 hasConceptScore W2065792998C139066938 @default.
• W2065792998 hasConceptScore W2065792998C155647269 @default.
• W2065792998 hasConceptScore W2065792998C178790620 @default.
• W2065792998 hasConceptScore W2065792998C181500209 @default.
• W2065792998 hasConceptScore W2065792998C185544564 @default.
• W2065792998 hasConceptScore W2065792998C185592680 @default.
• W2065792998 hasConceptScore W2065792998C2780407432 @default.
• W2065792998 hasConceptScore W2065792998C2780471494 @default.
• W2065792998 hasConceptScore W2065792998C2780567667 @default.
• W2065792998 hasConceptScore W2065792998C33062035 @default.
• W2065792998 hasConceptScore W2065792998C71240020 @default.
• W2065792998 hasConceptScore W2065792998C75079739 @default.
• W2065792998 hasConceptScore W2065792998C75473681 @default.
• W2065792998 hasIssue "4" @default.
• W2065792998 hasLocation W20657929981 @default.
• W2065792998 hasLocation W20657929982 @default.
• W2065792998 hasOpenAccess W2065792998 @default.
• W2065792998 hasPrimaryLocation W20657929981 @default.
• W2065792998 hasRelatedWork W2009514325 @default.
• W2065792998 hasRelatedWork W2009614525 @default.
• W2065792998 hasRelatedWork W2035337179 @default.
• W2065792998 hasRelatedWork W2071434581 @default.
• W2065792998 hasRelatedWork W2086191285 @default.
• W2065792998 hasRelatedWork W2100732097 @default.
• W2065792998 hasRelatedWork W2112270106 @default.
• W2065792998 hasRelatedWork W2171283905 @default.
• W2065792998 hasRelatedWork W2397405551 @default.
• W2065792998 hasRelatedWork W2952108123 @default.
• W2065792998 hasVolume "70" @default.
• W2065792998 isParatext "false" @default.
• W2065792998 isRetracted "false" @default.
• W2065792998 magId "2065792998" @default.
• W2065792998 workType "article" @default.