Matches in SemOpenAlex for { <https://semopenalex.org/work/W2065809932> ?p ?o ?g. }
Showing items 1 to 87 of
87
with 100 items per page.
- W2065809932 endingPage "742" @default.
- W2065809932 startingPage "739" @default.
- W2065809932 abstract "The present study investigates the conditions of trifluoromethylation of various aromatic compounds via the Kolbe oxidation of trifluoroacetic acid. The preparative electrolyse conditions were first optimized on the laboratory scale using the trifluoromethylation of benzonitrile in acetonitrile solutions as a model case. Sodium or pyridinium trifluoroacetates were tried as a source of trifluoromethyl radicals, the partial neutralization of trifluoroacetic acid by pyridine provided the best yield of trifluoromethylbenzonitrile (46%). The trifluoromethylation of the other aromatic compounds such as acetophenone, benzaldehyde and nitrobenzene led to yields slightly lower than those observed in the case of benzonitrile. The trifluoromethylation of benzonitrile was then studied in a commercially available flow cell. Yields were consistent with those obtained on the laboratory scale." @default.
- W2065809932 created "2016-06-24" @default.
- W2065809932 creator A5045082766 @default.
- W2065809932 creator A5067522548 @default.
- W2065809932 creator A5068462218 @default.
- W2065809932 creator A5085447122 @default.
- W2065809932 date "1999-01-01" @default.
- W2065809932 modified "2023-10-18" @default.
- W2065809932 title "Trifluoromethylation of aromatic compounds via Kolbe electrolysis in pure organic solvent. Study on laboratory and pilot scale" @default.
- W2065809932 cites W1595097099 @default.
- W2065809932 cites W1596726273 @default.
- W2065809932 cites W1990597291 @default.
- W2065809932 cites W2010421936 @default.
- W2065809932 cites W2019048321 @default.
- W2065809932 cites W2028826343 @default.
- W2065809932 cites W2031389822 @default.
- W2065809932 cites W2034580697 @default.
- W2065809932 cites W2054342805 @default.
- W2065809932 cites W2058275167 @default.
- W2065809932 cites W2071308399 @default.
- W2065809932 cites W2094720956 @default.
- W2065809932 cites W2165186234 @default.
- W2065809932 cites W2313666305 @default.
- W2065809932 cites W2951323359 @default.
- W2065809932 cites W3024153873 @default.
- W2065809932 cites W38573453 @default.
- W2065809932 cites W2484246471 @default.
- W2065809932 doi "https://doi.org/10.1039/a901305i" @default.
- W2065809932 hasPublicationYear "1999" @default.
- W2065809932 type Work @default.
- W2065809932 sameAs 2065809932 @default.
- W2065809932 citedByCount "17" @default.
- W2065809932 countsByYear W20658099322012 @default.
- W2065809932 countsByYear W20658099322015 @default.
- W2065809932 countsByYear W20658099322016 @default.
- W2065809932 countsByYear W20658099322018 @default.
- W2065809932 countsByYear W20658099322020 @default.
- W2065809932 countsByYear W20658099322021 @default.
- W2065809932 countsByYear W20658099322022 @default.
- W2065809932 crossrefType "journal-article" @default.
- W2065809932 hasAuthorship W2065809932A5045082766 @default.
- W2065809932 hasAuthorship W2065809932A5067522548 @default.
- W2065809932 hasAuthorship W2065809932A5068462218 @default.
- W2065809932 hasAuthorship W2065809932A5085447122 @default.
- W2065809932 hasConcept C144000664 @default.
- W2065809932 hasConcept C161790260 @default.
- W2065809932 hasConcept C178790620 @default.
- W2065809932 hasConcept C185592680 @default.
- W2065809932 hasConcept C2775888733 @default.
- W2065809932 hasConcept C2776442012 @default.
- W2065809932 hasConcept C2777463227 @default.
- W2065809932 hasConcept C2779692420 @default.
- W2065809932 hasConcept C2779953769 @default.
- W2065809932 hasConcept C2780112151 @default.
- W2065809932 hasConcept C2780263894 @default.
- W2065809932 hasConceptScore W2065809932C144000664 @default.
- W2065809932 hasConceptScore W2065809932C161790260 @default.
- W2065809932 hasConceptScore W2065809932C178790620 @default.
- W2065809932 hasConceptScore W2065809932C185592680 @default.
- W2065809932 hasConceptScore W2065809932C2775888733 @default.
- W2065809932 hasConceptScore W2065809932C2776442012 @default.
- W2065809932 hasConceptScore W2065809932C2777463227 @default.
- W2065809932 hasConceptScore W2065809932C2779692420 @default.
- W2065809932 hasConceptScore W2065809932C2779953769 @default.
- W2065809932 hasConceptScore W2065809932C2780112151 @default.
- W2065809932 hasConceptScore W2065809932C2780263894 @default.
- W2065809932 hasIssue "7" @default.
- W2065809932 hasLocation W20658099321 @default.
- W2065809932 hasOpenAccess W2065809932 @default.
- W2065809932 hasPrimaryLocation W20658099321 @default.
- W2065809932 hasRelatedWork W1976313624 @default.
- W2065809932 hasRelatedWork W1976662127 @default.
- W2065809932 hasRelatedWork W2024752401 @default.
- W2065809932 hasRelatedWork W2065809932 @default.
- W2065809932 hasRelatedWork W2070842288 @default.
- W2065809932 hasRelatedWork W2094716250 @default.
- W2065809932 hasRelatedWork W2156333380 @default.
- W2065809932 hasRelatedWork W2167299753 @default.
- W2065809932 hasRelatedWork W2357069171 @default.
- W2065809932 hasRelatedWork W2951203795 @default.
- W2065809932 hasVolume "23" @default.
- W2065809932 isParatext "false" @default.
- W2065809932 isRetracted "false" @default.
- W2065809932 magId "2065809932" @default.
- W2065809932 workType "article" @default.