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- W2065810900 abstract "The new ligand bis(2-picolyl)(2-hydroxy-3,5-di-tert-butylbenzyl)amine (HL) was prepared from bis(2-picolyl)amine and 2,4-di-tert-butyl-6-(chloromethyl)phenol. It acts as a tetradentate N,N,O tripod ligand ensuring 5-fold coordination in all its zinc complexes L.Zn-X. The central complex of the series was [L.Zn(OH(2))]ClO(4) (1) obtained from zinc perchlorate. Together with the more labile complex L.Zn-C(2)H(5) (2), obtained from diethyl zinc, it was used as a starting material for ligand substitutions. In the presence of bases, 1 was converted to L.Zn-OH (3), [L.Zn(py)]ClO(4) (4), and [(L.Zn)(3)(mu(3)-CO(3))]ClO(4) (5). Metathetical reactions produced the neutral complexes L.Zn-X with X = Br (6), OAc (7), OC(6)H(5) (8), SC(6)H(5) (9), OP(O)(OPh)(2) (10), p-nitrophenolate (11), 1-methyluracilate (12), o-formylphenolate (13), and o-hydroxymethylphenolate (14). Structure determinations of 1, 5, 7, 10, 11, 13, and 14 confirmed the strictly monodentate attachment of all units X in L.Zn-X. The hydrolytic cleavage of tris(p-nitrophenyl) phosphate by 1 was investigated preparatively and kinetically. L.Zn-OH was found to be the hydrolytically active nucleophile. The second-order rate constant for the cleavage reaction was found to be slightly lower than the values for related systems, reflecting the steric hindrance in the tert-butyl-substituted ligand L." @default.
- W2065810900 created "2016-06-24" @default.
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- W2065810900 date "2001-04-11" @default.
- W2065810900 modified "2023-09-30" @default.
- W2065810900 title "A Sterically Hindered N,N,O Tripod Ligand and Its Zinc Complex Chemistry" @default.
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- W2065810900 cites W1968539554 @default.
- W2065810900 cites W1971396056 @default.
- W2065810900 cites W1976138536 @default.
- W2065810900 cites W1976279760 @default.
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- W2065810900 cites W1985890785 @default.
- W2065810900 cites W1987929829 @default.
- W2065810900 cites W1989360530 @default.
- W2065810900 cites W1991288377 @default.
- W2065810900 cites W1995713751 @default.
- W2065810900 cites W1997855174 @default.
- W2065810900 cites W1999687041 @default.
- W2065810900 cites W2002489252 @default.
- W2065810900 cites W2005596115 @default.
- W2065810900 cites W2006775197 @default.
- W2065810900 cites W2007934301 @default.
- W2065810900 cites W2009220847 @default.
- W2065810900 cites W2009232720 @default.
- W2065810900 cites W2026180730 @default.
- W2065810900 cites W2030341954 @default.
- W2065810900 cites W2031910120 @default.
- W2065810900 cites W2035692041 @default.
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- W2065810900 cites W2049115197 @default.
- W2065810900 cites W2052835643 @default.
- W2065810900 cites W2052887427 @default.
- W2065810900 cites W2053396558 @default.
- W2065810900 cites W2054028437 @default.
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- W2065810900 doi "https://doi.org/10.1021/ic001204j" @default.
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