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- W2065823805 abstract "The quantum theory of the pressure dependence of collision induced intersystem crossing is developed in the impact limit where collision times are short compared to time scales for molecular decay. A basic model is introduced which contains singlet–triplet intramolecular couplings and collisional processes that correspond in a pure spin basis to dephasing of singlet–triplet and triplet–triplet coherences and to triplet state population decay. Expressions are derived for the ratio of the emission yield at zero pressure divided by that at pressure p in the separate limits of low triplet level density and of short triplet–triplet coherence lifetimes. The first order corrections to the latter case are found to be negligible over a wide range of pressure and molecular parameters. The theory shows that pressure saturation of collision induced intersystem crossing emerges from a competition between dephasing and population decay processes induced by the collider. A strong sensitivity is exhibited to the minimum zeroth order singlet–triplet splitting." @default.
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- W2065823805 date "1985-12-15" @default.
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- W2065823805 title "Quantum theory of the full pressure dependence of collision induced intersystem crossing" @default.
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- W2065823805 doi "https://doi.org/10.1063/1.449579" @default.
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