FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2065839377> ?p ?o ?g. }

• W2065839377 endingPage "2105" @default.
• W2065839377 startingPage "2099" @default.
• W2065839377 abstract "Anions are oxidatively added to nitronate anions to yield α-substituted nitroalkanes when potassium hexacyanoferrate(III) is used as oxidant. Oxidation of nitronate anions yields intermediate anitroalkyl radicals, which undergo addition by anions to give intermediate α-substituted nitroalkane radical anions, which are further oxidised to yield the α-substituted nitroalkanes. The nitronate anions used are derived from 5-nitrohex-1-ene, 6-nitrohept-1-ene, endo-5-nitro-exo-6-phenylbicyclo[2.2.1 ]hept-2-ene, and 1-(bicyclo[2.2.1 ]hept-5-en-endo-2-yl)-2-nitropropane. The intermediate α-nitroalkyl radicals underwent addition of anions to form radical anions faster than intramolecular cyclisation onto the ω-alkenes. The α-nitroalkyl radical derived from 1-(bicyclo[2.2.1 ]hept-5-en-endo-2yl)-2-nitropropane underwent cyclisation when the oxidation was carried out in the absence of an added anion. The addition of anions (thiocyanate, benzenesulfinate, 4-chlorobenzenethiolate, and nitrite) to the α-nitroalkyl radicals derived from endo-5-nitro-exo-6-phenylbicyclo[2.2.1]hept-2-ene occurred stereoselectively from the less hindered exo face. Oxidative addition of 4-chlorobenzenethiolate to the nitronate from endo-5-nitro-exo-6-phenylbicyclo[2.2.1]hept-2-ene gave an unusual cyclisation via addition of a thiyl radical to the alkene." @default.
• W2065839377 created "2016-06-24" @default.
• W2065839377 creator A5010159692 @default.
• W2065839377 creator A5010229982 @default.
• W2065839377 creator A5067475791 @default.
• W2065839377 creator A5005807277 @default.
• W2065839377 date "1993-01-01" @default.
• W2065839377 modified "2023-10-12" @default.
• W2065839377 title "Oxidative addition reactions of ω-alkenyl nitronate anions" @default.
• W2065839377 cites W1965047429 @default.
• W2065839377 cites W1965161486 @default.
• W2065839377 cites W1966664736 @default.
• W2065839377 cites W1974568440 @default.
• W2065839377 cites W1975462615 @default.
• W2065839377 cites W1991570249 @default.
• W2065839377 cites W1991890152 @default.
• W2065839377 cites W1998401328 @default.
• W2065839377 cites W2007938276 @default.
• W2065839377 cites W2010752429 @default.
• W2065839377 cites W2014867550 @default.
• W2065839377 cites W2020390172 @default.
• W2065839377 cites W2020811238 @default.
• W2065839377 cites W2022919510 @default.
• W2065839377 cites W2031882534 @default.
• W2065839377 cites W2038127756 @default.
• W2065839377 cites W2038522081 @default.
• W2065839377 cites W2040153871 @default.
• W2065839377 cites W2044783443 @default.
• W2065839377 cites W2060554135 @default.
• W2065839377 cites W2060766436 @default.
• W2065839377 cites W2063468450 @default.
• W2065839377 cites W2074019626 @default.
• W2065839377 cites W2075829117 @default.
• W2065839377 cites W2090591453 @default.
• W2065839377 cites W2106520010 @default.
• W2065839377 cites W2111015693 @default.
• W2065839377 cites W2120653192 @default.
• W2065839377 cites W2132037995 @default.
• W2065839377 cites W2147392577 @default.
• W2065839377 cites W2149155105 @default.
• W2065839377 cites W2342635991 @default.
• W2065839377 cites W2853990330 @default.
• W2065839377 cites W2950485537 @default.
• W2065839377 cites W2950597179 @default.
• W2065839377 cites W2951675450 @default.
• W2065839377 cites W2955597942 @default.
• W2065839377 cites W4247440618 @default.
• W2065839377 cites W4251500918 @default.
• W2065839377 doi "https://doi.org/10.1039/p19930002099" @default.
• W2065839377 hasPublicationYear "1993" @default.
• W2065839377 type Work @default.
• W2065839377 sameAs 2065839377 @default.
• W2065839377 citedByCount "9" @default.
• W2065839377 countsByYear W20658393772012 @default.
• W2065839377 countsByYear W20658393772020 @default.
• W2065839377 crossrefType "journal-article" @default.
• W2065839377 hasAuthorship W2065839377A5005807277 @default.
• W2065839377 hasAuthorship W2065839377A5010159692 @default.
• W2065839377 hasAuthorship W2065839377A5010229982 @default.
• W2065839377 hasAuthorship W2065839377A5067475791 @default.
• W2065839377 hasConcept C134121241 @default.
• W2065839377 hasConcept C139066938 @default.
• W2065839377 hasConcept C145148216 @default.
• W2065839377 hasConcept C155647269 @default.
• W2065839377 hasConcept C178790620 @default.
• W2065839377 hasConcept C185592680 @default.
• W2065839377 hasConcept C191897082 @default.
• W2065839377 hasConcept C192562407 @default.
• W2065839377 hasConcept C24961977 @default.
• W2065839377 hasConcept C2776343937 @default.
• W2065839377 hasConcept C27777614 @default.
• W2065839377 hasConcept C2780263894 @default.
• W2065839377 hasConcept C2780639532 @default.
• W2065839377 hasConcept C30095370 @default.
• W2065839377 hasConcept C71240020 @default.
• W2065839377 hasConcept C75079739 @default.
• W2065839377 hasConcept C75473681 @default.
• W2065839377 hasConceptScore W2065839377C134121241 @default.
• W2065839377 hasConceptScore W2065839377C139066938 @default.
• W2065839377 hasConceptScore W2065839377C145148216 @default.
• W2065839377 hasConceptScore W2065839377C155647269 @default.
• W2065839377 hasConceptScore W2065839377C178790620 @default.
• W2065839377 hasConceptScore W2065839377C185592680 @default.
• W2065839377 hasConceptScore W2065839377C191897082 @default.
• W2065839377 hasConceptScore W2065839377C192562407 @default.
• W2065839377 hasConceptScore W2065839377C24961977 @default.
• W2065839377 hasConceptScore W2065839377C2776343937 @default.
• W2065839377 hasConceptScore W2065839377C27777614 @default.
• W2065839377 hasConceptScore W2065839377C2780263894 @default.
• W2065839377 hasConceptScore W2065839377C2780639532 @default.
• W2065839377 hasConceptScore W2065839377C30095370 @default.
• W2065839377 hasConceptScore W2065839377C71240020 @default.
• W2065839377 hasConceptScore W2065839377C75079739 @default.
• W2065839377 hasConceptScore W2065839377C75473681 @default.
• W2065839377 hasIssue "17" @default.
• W2065839377 hasLocation W20658393771 @default.
• W2065839377 hasOpenAccess W2065839377 @default.
• W2065839377 hasPrimaryLocation W20658393771 @default.

• next