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- W2065847939 abstract "Recently, special interest has been devoted to the group ofcopper(II) complexes containing Schiff bases, derived fromsalicylaldehyde and various amino acids, and N-, or O- donorneutral ligands due to their biological activities. From this group of substances the structures of (N- salicylidene-racglutamato)(1-methylimidazole)Cu(II), (N-salicylidenerac-glutamato)(2-methylimidazole)Cu(II), (N-salicylidene-L-glutamato)(2-ethylimidazole)Cu(II) and aqua(Nsalicylidene-methylester-L-glutamato)Cu(II)monohydrate have been determined. Electronic structure of these compounds has been investigated by the B3LYP method. A continuation of these studies is a new complex transbis(ethanol)tetrakis(imidazole)Cu(II)(2+) bis[µ-(N-salicylidene-L-glutamato-N,O)-κO:κO´-(imidazole)Cu(II)](2-)presented here.This complex has quite spectacular structural features. Bothions are located on inverse centre. The cation is mononuclear, while the anion is binuclear. The quantum chemical calculation of the electronic structure has also been done by the B3LYP method." @default.
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- W2065847939 date "2004-01-01" @default.
- W2065847939 modified "2023-10-14" @default.
- W2065847939 title "Novel type of Cu(II) complex containing Schiff base" @default.
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