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- W2065850611 abstract "Abstract The compounds (η5-RC5H4)(η3-C3H5)2Cr (R = H, Me, t-C4H9) and (η5-indenyl)(η3-C3H5)2Cr react with alkynes (RC2R) with displacement of 1,5-hexadiene to give Cp′(η6-R6C6)Cr species. Treatment with cyclooctatetraene gives compounds containing an η6-C8H8 group while the final product of the reaction with cycloheptatriene contains an η7-cycloheptatrienyl fragment. 1,3-Butadiene reacts with dimerization to give the diamagnetic, dinuclear species (Cp′Cr)2(μ-η3,η3-C8H12). The molecular structures of Cp(η6-Me6C6)Cr, (η5-indenyl)(η6-Me6C6)CR and Cp(η6-C8H8)Cr have been confirmed by X-ray diffraction." @default.
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- W2065850611 date "1993-11-01" @default.
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- W2065850611 title "Organochromium π-complexes—VII. The reactions of Cp(η3-allyl)2Cr compounds with alkynes and alkenes" @default.
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- W2065850611 doi "https://doi.org/10.1016/s0277-5387(00)80116-3" @default.
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