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• W2065853531 endingPage "2638" @default.
• W2065853531 startingPage "2631" @default.
• W2065853531 abstract "The bis(trimethylsilyl)-substituted hydroxycyclopentadienyl ruthenium hydride [2,5-(SiMe(3))(2)-3,4-(CH(2)OCH(2))(η(5)-C(4)COH)]Ru(CO)(2)H (10) is an efficient catalyst for hydrogenation of aldehydes and ketones. Because 10 transfers hydrogen rapidly to aldehydes and ketones and because it does not form an inactive bridging hydride during reaction, hydrogenation of aldehydes and ketones can be performed at room temperature under relatively low hydrogen pressure (3 atm); this is a significant improvement compared with previously developed Shvo type catalysts. Kinetic and (2)H NMR spectroscopic studies of the stoichiometric reduction of aldehydes and ketones by 10 established a two-step process for the hydrogen transfer: (1) rapid and reversible hydrogen bond formation between OH of 10 and the oxygen of the aldehyde or ketone, (2) followed by slow transfer of both proton and hydride from 10 to the aldehyde or ketone. The stoichiometric and catalytic activities of complex 10 are compared to those of other Shvo type ruthenium hydrides and related iron hydrides." @default.
• W2065853531 created "2016-06-24" @default.
• W2065853531 creator A5062126454 @default.
• W2065853531 creator A5071663698 @default.
• W2065853531 date "2011-10-21" @default.
• W2065853531 modified "2023-10-14" @default.
• W2065853531 title "Trimethylsilyl-Substituted Hydroxycyclopentadienyl Ruthenium Hydrides as Benchmarks To Probe Ligand and Metal Effects on the Reactivity of Shvo Type Complexes" @default.
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• W2065853531 doi "https://doi.org/10.1021/om2007453" @default.
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