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• W2065857525 abstract "The complex trans-[Rh2{µ-1,8-(NH)2C10H6}(CO)2(PPh3)2](1) reacts with [M(PPh3)]+(M = Au, Ag, or Cu) to give [Rh2{µ-M(PPh3)}{µ-1,8-(NH)2C10H6}(CO)2(PPh3)2]ClO4(2)–(4). Compound (2) was analysed by single-crystal X-ray diffraction: triclinic, space group Pa= 14.358(4), b= 20.775(6), c= 13.184(3)Å, α= 105.65(3), β= 115.66(2), γ= 69.96(3)°, Z= 2, and R= 0.071. The basic skeleton consists of a Rh2Au triangle, the two Rh–Au distances [2.797(2) and 2.690(2)Å] being consistent with Rh–Au bonds. The co-ordination geometry around the rhodium atoms is square pyramidal. The Rh–Rh separation [2.815(2)Å] is at the upper part of the range of distances for a single Rh–Rh bond. Phosphorus-31 n.m.r. and i.r. data for compounds (2)–(4) are described, and are consistent with a bridging disposition of the M (PPh3) group in all the complexes." @default.
• W2065857525 created "2016-06-24" @default.
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• W2065857525 date "1989-01-01" @default.
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• W2065857525 title "Reaction of [Rh₂{µ-1,8-(NH)₂C₁₀H₆}(CO)₂(PPh₃)₂] with [M(PPh₃)]⁺(M = Au, Ag, or Cu): formation of unusual 44-electron Rh₂M clusters. Crystal structure of [Rh₂{µ-Au(PPh₃)}{µ-1,8-(NH)₂C₁₀H₆}(CO)₂(PPh₃)₂]ClO₄·2CH₂Cl₂" @default.
• W2065857525 doi "https://doi.org/10.1039/dt9890001249" @default.
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