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- W2065868150 abstract "A dinuclear Co complex with bis(pyridyl)pyrazolato (bpp(-)) and terpyridine (trpy) ligands, [Co(III)2(trpy)2(μ-bpp)(OH)(OH2)](4+) (1(4+)), undergoes three-electron reduction by cobaltocene in acetonitrile to produce 1(+), which is in the protonation equilibrium with the Co(II)Co(III)-hydride complex, and the further protonation of the hydride by trifluoroacetic acid yields hydrogen quantitatively. The kinetic study together with the detection of the Co(II)Co(III)-hydride complex revealed the mechanism of the hydrogen production by the reaction of 1(+) with trifluoroacetic acid." @default.
- W2065868150 created "2016-06-24" @default.
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- W2065868150 date "2013-10-01" @default.
- W2065868150 modified "2023-10-11" @default.
- W2065868150 title "Protonation Equilibrium and Hydrogen Production by a Dinuclear Cobalt–Hydride Complex Reduced by Cobaltocene with Trifluoroacetic Acid" @default.
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- W2065868150 doi "https://doi.org/10.1021/ja408080z" @default.
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