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- W2065903214 abstract "A palladium complex immobilized in a thin film of a silica-supported ionic liquid was developed which served as a bifunctional catalyst with soft Lewis acidic and strong Brønsted acidic functions. Thus, silica (aerosol 355, 150 m2/g; 5.0 g) was impregnated with a solution of Pd(CF3CO2)2 (133 mg), DPPF (333 mg) and TfOH (150 mg; Pd2+/H+ = 10:1) in EMIm (2.5 mL) to give a free-flowing powder of the immobilized catalyst (Pd contents: 0.044 mmol Pd2+/g cat.). A bed reactor was filled with the catalyst (50 mg) and glass beads (remaining volume), and a solution of aniline with styrene in heptane passed through the reactor at 150-300 °C. The conversion attained a maximum of 35% at 240 °C." @default.
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- W2065903214 date "2006-11-01" @default.
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- W2065903214 title "Hydroamination Catalyzed by a Pd Catalyst Immobilized in a Thin Film" @default.
- W2065903214 doi "https://doi.org/10.1055/s-2006-949406" @default.
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