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- W2065921884 abstract "Tsuji–Trost reaction (Pd-catalyzed allylic alkylation) of CF<sub>3</sub>-containing esters with three electron-withdrawing groups is reported. The reactions with methyl bis(trifluoromethyl)acetate and dimethyl (trifluoromethyl)malonate were carried out with low-loading catalysts of Pd(0) and XPhos at ambient temperature in THF, giving the products in high yields. This method efficiently overcomes the β-defluorination, which is hard to control in the chemical transformation of α-trifluoromethyl carbanions, and provides versatile fluorinated compounds with quaternary carbon centers, which are highly demanded in drug discovery." @default.
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- W2065921884 date "2013-02-20" @default.
- W2065921884 modified "2023-09-27" @default.
- W2065921884 title "Pd-Catalyzed Allylic Alkylation of CF3-Containing Esters with Three Electron-Withdrawing Groups" @default.
- W2065921884 doi "https://doi.org/10.1055/s-0032-1318313" @default.
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