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- W2065928146 abstract "Abstract We report the first room-temperature stable triplet π-aryl based carbene, 2,2′,4,4′,6,6′,-hexabromodiphenylmethylene 2 in both crystals and fluid solutions. This paper describes ESR detection of 2 in the crystal of the diazo precursor 1 and the molecular and crystal structure of the precursor obtained by X-ray diffraction at room temperature. The crystal is monoclinic with cell dimensions, a= 9.993Å, b = 13.261Å, c= 12.743 Å, θ= 91.88°, Z= 4, and the space group P2i/n. The two phenyl rings of 2,4,6-bromo-substitution make bent perpendicular conformation with 139 degree of the bond angle at the diazo methane. Non-bonded contacts shorter than the van der Waals radii were found between the nitrogen and bromine atoms of the nearest neighboring molecules." @default.
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- W2065928146 date "1996-03-01" @default.
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- W2065928146 title "Electronic and Molecular Structures of Room-Temperature Stable Triplet Carbene as Studied by ESR and X-Ray Crystal Analysis of the Diazo Precursor" @default.
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- W2065928146 doi "https://doi.org/10.1080/10587259608033682" @default.
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