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- W2065956721 abstract "The incubation of 3α,15β-dihydroxy-ent-kaur-16-ene (1) with the fungus Gibberella fujikuroi gave 3α,7α,15β-trihydroxy-ent-kaur-16-ene (5), 3α,11β,15β-trihydroxy-ent-kaur-16-ene (13), and 3α,7α,11β,15β-tetrahydroxy-ent-kaur-16-ene (17). The ether 3α,15β-dihydroxy-11β,16β-epoxy-ent-kaurane (15) and the isomerized compounds 3α,7α-dihydroxy-15-oxo-ent-(16S)-kaurane (8) and 3α,7α,11β-trihydroxy-15-oxo-ent-(16S)-kaurane (10) were also obtained. The incubation of 3α-hydroxy-15-oxo-ent-(16S)-kaurane (7) with the fungus also afforded compounds 8 and 10, as well as 3α,11β-dihydroxy-15-oxo-ent-(16S)-kaurane (20), 3α,6α,11β-trihydroxy-15-oxo-ent-(16S)-kaurane, (22) 3α,6β,7α-trihydroxy-15-oxo-ent-(16S)-kaurane (25), and 3α,11β,16α-trihydroxy-15-oxo-ent-(16S)-kaurane (27). These results indicate that in 3,15-oxygenated ent-kaurane derivatives the presence of a 3α-hydroxyl inhibits oxidation at C-19, while a 15β-hydroxyl or a 15-oxo group directs hydroxylation at C-11(β) and C-7(α)." @default.
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- W2065956721 date "1996-01-01" @default.
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- W2065956721 title "The Biotransformation of Two 3,15-Oxygenate <i>ent</i>-Kaurane Derivatives by <i>Gibberella fujikuroi</i>" @default.
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- W2065956721 doi "https://doi.org/10.1021/np960405q" @default.
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