FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2065976988> ?p ?o ?g. }

• W2065976988 endingPage "1144" @default.
• W2065976988 startingPage "1132" @default.
• W2065976988 abstract "The reaction of the α-stabilized bis-ylide [Ph3PC(CO2Me)−C(CO2Me)PPh3] with M(II) bis-solvato derivatives, cis-[M(C6F5)2(OC4H8)2] or [M(C∧X)(OC4H8)2]ClO4 (M = Pd, Pt; C∧X = orthometalated ligand), yields the ylide-carbene complexes cis-[M(C6F5)2{C(CO2Me)−C(CO2Me)(PPh3)}(PPh3)] (M = Pt 1a, Pd 1b) or [M(C∧X){C(CO2Me)−C(CO2Me)(PPh3)}(PPh3)]ClO4 (M = Pt, C∧X = o-CH2C6H4P(o-tolyl)2, 2; M = Pd, C∧X = o-CH2C6H4P(o-tolyl)2, 3; CH2C9H6N-C8,N, 4; NC5H4-o-C6H4, 5; C13H8N, 6). The reaction appears to proceed with PC bond cleavage, generating a carbene-ylide ligand [:C(CO2Me)−C(CO2Me)PPh3] and a PPh3 group, both coordinated to the metal center. The reaction of the solvato complexes [M(C∧X)(OC4H8)(PPh3)]ClO4 with the bis-ylide results in the selective formation of [M(C∧X)(PPh3)2]ClO4 (M = Pt, C∧X = o-CH2C6H4P(o-tolyl)2, 7; M = Pd, C∧X = CH2C9H6N-C8,N, 8), showing that when one vacant position is available, only the PPh3 group binds to the metal center, and the carbene fragment decomposes to OPPh3 and dimethylfumarate. On the other hand, the reaction of the bis-solvato precursors [Pd(C6F5)(L)(OC4H8)2]ClO4 with the bis-ylide yields the corresponding metallacyclopropane [Pd{trans-C(C6F5)(CO2Me)−C(PPh3)(CO2Me)}(L)(PPh3)](ClO4) (L = SC4H8, 9; PPh3, 10), probably through the initial formation of an ylide-carbene complexsimilar to 1−6followed by the migratory insertion of the carbene ligand into the Pd−C(C6F5) bond and coordination of the newly generated ylide function. The crystal structure of complex 1a·CH2Cl2 has been analyzed by X-ray diffraction." @default.
• W2065976988 created "2016-06-24" @default.
• W2065976988 creator A5023875681 @default.
• W2065976988 creator A5038678975 @default.
• W2065976988 creator A5058748323 @default.
• W2065976988 creator A5082630205 @default.
• W2065976988 creator A5083225216 @default.
• W2065976988 date "2003-02-05" @default.
• W2065976988 modified "2023-10-14" @default.
• W2065976988 title "Stabilized Bis-ylides as a Source of Carbene Ligands in Palladium(II) and Platinum(II) Complexes" @default.
• W2065976988 cites W1521632659 @default.
• W2065976988 cites W1530520006 @default.
• W2065976988 cites W1970897691 @default.
• W2065976988 cites W1971386066 @default.
• W2065976988 cites W1971727641 @default.
• W2065976988 cites W1979123294 @default.
• W2065976988 cites W1986510412 @default.
• W2065976988 cites W1987016519 @default.
• W2065976988 cites W1988335155 @default.
• W2065976988 cites W1988489187 @default.
• W2065976988 cites W1990537569 @default.
• W2065976988 cites W1992122100 @default.
• W2065976988 cites W1994344970 @default.
• W2065976988 cites W1996742069 @default.
• W2065976988 cites W1997084636 @default.
• W2065976988 cites W2000994711 @default.
• W2065976988 cites W2001113145 @default.
• W2065976988 cites W2004103003 @default.
• W2065976988 cites W2009452421 @default.
• W2065976988 cites W2010969604 @default.
• W2065976988 cites W2011193606 @default.
• W2065976988 cites W2012995996 @default.
• W2065976988 cites W2014722790 @default.
• W2065976988 cites W2014736311 @default.
• W2065976988 cites W2014766433 @default.
• W2065976988 cites W2020831071 @default.
• W2065976988 cites W2021215906 @default.
• W2065976988 cites W2022276838 @default.
• W2065976988 cites W2026503010 @default.
• W2065976988 cites W2026999832 @default.
• W2065976988 cites W2032139582 @default.
• W2065976988 cites W2032471875 @default.
• W2065976988 cites W2034225121 @default.
• W2065976988 cites W2035121833 @default.
• W2065976988 cites W2035172092 @default.
• W2065976988 cites W2036075158 @default.
• W2065976988 cites W2037258850 @default.
• W2065976988 cites W2039930479 @default.
• W2065976988 cites W2045515675 @default.
• W2065976988 cites W2047507566 @default.
• W2065976988 cites W2048135281 @default.
• W2065976988 cites W2051138437 @default.
• W2065976988 cites W2056575028 @default.
• W2065976988 cites W2058634889 @default.
• W2065976988 cites W2060034565 @default.
• W2065976988 cites W2062556673 @default.
• W2065976988 cites W2062841015 @default.
• W2065976988 cites W2062987969 @default.
• W2065976988 cites W2064629625 @default.
• W2065976988 cites W2066179753 @default.
• W2065976988 cites W2066812994 @default.
• W2065976988 cites W2072731064 @default.
• W2065976988 cites W2073086124 @default.
• W2065976988 cites W2074385244 @default.
• W2065976988 cites W2075942477 @default.
• W2065976988 cites W2082055653 @default.
• W2065976988 cites W2082993068 @default.
• W2065976988 cites W2090210629 @default.
• W2065976988 cites W2094326551 @default.
• W2065976988 cites W2095014741 @default.
• W2065976988 cites W2095411597 @default.
• W2065976988 cites W2097737512 @default.
• W2065976988 cites W2100081839 @default.
• W2065976988 cites W2124498560 @default.
• W2065976988 cites W2148066840 @default.
• W2065976988 cites W2150335900 @default.
• W2065976988 cites W2152799402 @default.
• W2065976988 cites W2157121890 @default.
• W2065976988 cites W2327993047 @default.
• W2065976988 cites W2330222196 @default.
• W2065976988 cites W2950402213 @default.
• W2065976988 cites W2952013501 @default.
• W2065976988 cites W2952219580 @default.
• W2065976988 cites W4230828331 @default.
• W2065976988 cites W4254139058 @default.
• W2065976988 cites W1988486020 @default.
• W2065976988 doi "https://doi.org/10.1021/om020467d" @default.
• W2065976988 hasPublicationYear "2003" @default.
• W2065976988 type Work @default.
• W2065976988 sameAs 2065976988 @default.
• W2065976988 citedByCount "21" @default.
• W2065976988 countsByYear W20659769882013 @default.
• W2065976988 countsByYear W20659769882015 @default.
• W2065976988 countsByYear W20659769882016 @default.
• W2065976988 countsByYear W20659769882018 @default.
• W2065976988 countsByYear W20659769882019 @default.
• W2065976988 crossrefType "journal-article" @default.
• W2065976988 hasAuthorship W2065976988A5023875681 @default.

• next