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- W2065977207 abstract "The phosphatriafulvene complex 1 is sulfurized at phosphorus by reaction with propylene sulfide at room temperature. The X-ray crystal structure of 2 shows a long P−S bond (2.0039(5) Å) compatible with a zwitterionic formulation. The reaction of 1 with propylene oxide takes place at 110 °C and leads to the ring-expanded 1-phosphacyclobutenone 3. DFT calculations support the intermediacy of a phosphatriafulvene epoxide and its rearrangement to a four-membered ring, paralleling the oxaspiropentene−cyclobutenone conversion." @default.
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- W2065977207 date "2010-03-08" @default.
- W2065977207 modified "2023-09-23" @default.
- W2065977207 title "The Phosphorus Version of the Oxaspiropentene−Cyclobutenone Rearrangement" @default.
- W2065977207 doi "https://doi.org/10.1021/om900983k" @default.
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