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- W2065982661 abstract "Raman longitudinal acoustic mode (LAM) spectra have been obtained during isothermal crystallization from the melt at various temperatures of a poly(ethylene oxide) (PEO) fraction of molecular weight about 3000. At all temperatures, we find an initial single well-defined LAM band corresponding to a helical chain length that represents a non-integral-fold (NIF) structure. With time, and more rapidly at higher crystallization temperatures, the NIF chains transform into integer-fold (IF) structures. The final morphology consists of IF mixed crystals composed mainly of extended (E) chains but with once-folded (F2) chains embedded in them. This solid-state transformation from the NIF state may proceed through the F2 state." @default.
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- W2065982661 date "1996-01-01" @default.
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- W2065982661 title "Raman Longitudinal Acoustic Mode Studies of a Poly(ethylene oxide) Fraction during Isothermal Crystallization from the Melt" @default.
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- W2065982661 doi "https://doi.org/10.1021/ma960331p" @default.
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