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- W2065987256 abstract "An inherently chiral ABii diphosphonato cavitand (±)-4 bearing a single quinoxaline bridging moiety was synthesized and resolved by chiral HPLC. Its chiroptical properties were investigated and VCD experiments allowed the determination of its absolute configuration. Distinguishable diastereomeric complexes in solution with l-adrenaline were observed by 1H and 31P NMR together with a noticeable enantio-discrimination at 253 K (dr ∼2:1) in favor of the dextrorotatory cavitand (+)-4." @default.
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- W2065987256 date "2010-06-01" @default.
- W2065987256 modified "2023-10-01" @default.
- W2065987256 title "The absolute configuration of an inherently chiral phosphonatocavitand and its use toward the enantioselective recognition of l-adrenaline" @default.
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- W2065987256 doi "https://doi.org/10.1016/j.tetasy.2010.03.028" @default.
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