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- W2065987780 startingPage "173" @default.
- W2065987780 abstract "The rate constant for the transfer of a ${ensuremath{nu}}_{3}$ quantum from C${mathrm{O}}_{2}$ to ${mathrm{N}}_{2}$O is calculated using a second-order formulation of the theory of energy transfer due to long-range forces. This formulation is valid if ${ensuremath{omega}}_{mathrm{vi}}ensuremath{tau}>1$, where ${ensuremath{omega}}_{mathrm{vi}}$ is the frequency (rad ${mathrm{sec}}^{ensuremath{-}1}$) for transition from initial to virtual state, and $ensuremath{tau}$ is the time duration of the collision. The theory is estimated to be accurate to within a factor of 2 and agrees with the room-temperature experimental results. The formulation is also generalized to include energy transfer due to Debye induction interactions." @default.
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- W2065987780 date "1970-07-01" @default.
- W2065987780 modified "2023-09-26" @default.
- W2065987780 title "Transfer of Vibrational Energy from Asymmetric Stretch of CO2toν3ofN2O" @default.
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- W2065987780 doi "https://doi.org/10.1103/physreva.2.173" @default.
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