FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2065994067> ?p ?o ?g. }

• W2065994067 endingPage "3421" @default.
• W2065994067 startingPage "3412" @default.
• W2065994067 abstract "The synthesis and photophysical properties of two new Re(I) complexes are reported: fac-Re(phenC⋮CH)(CO)3Cl (where phenC⋮CH is 5-ethynyl-1,10-phenanthroline) and its Au(I)-acetylide analogue (fac-Re(phenC⋮CAuPPh3)(CO)3Cl). Also reported are the photophysical measurements obtained for the benchmark fac-Re(phen)(CO)3Cl chromophore, as well as the phenC⋮CAuPPh3 and phenC⋮CH ligands. The unstable nature of the precursor gold-containing ligand illustrates the advantage of using the “chemistry on the complex” approach, which facilitated preparation of the Re−Au binuclear complex. Where possible, all compounds were studied by static and transient absorption (TA), as well as steady-state and time-resolved photoluminescence (TRPL), at room temperature (RT) and 77 K, as well as nanosecond time-resolved infrared (TRIR) spectroscopy. The spectroscopic information provided by these techniques enabled a thorough evaluation of excited-state decay in most cases. In fac-Re(phenC⋮CH)(CO)3Cl, the RT excited-state decay is most consistent with a metal-to-ligand charge transfer (MLCT) assignment, whereas at 77 K, the lowest excited state is dominated by the triplet intraligand (3IL) state, localized within the diimine ligand. The lowest excited state in fac-Re(phenC⋮CAuPPh3)(CO)3Cl seems to result from an admixture of Re-based MLCT and 3IL states resident on the phenC⋮CAuPPh3 moiety. TA and TRIR methods indicate that these excited states are thermally equilibrated at room temperature. At 77 K, the MLCT energy of fac-Re(phenC⋮CAuPPh3)(CO)3Cl is increased as a result of the glassy medium and the resulting excited state can be considered to be ligand-localized." @default.
• W2065994067 created "2016-06-24" @default.
• W2065994067 creator A5011274974 @default.
• W2065994067 creator A5017888744 @default.
• W2065994067 creator A5083979016 @default.
• W2065994067 date "2005-04-12" @default.
• W2065994067 modified "2023-09-27" @default.
• W2065994067 title "Influence of a Gold(I)−Acetylide Subunit on the Photophysics of Re(Phen)(CO)₃Cl" @default.
• W2065994067 cites W1970684567 @default.
• W2065994067 cites W1972177468 @default.
• W2065994067 cites W1975584921 @default.
• W2065994067 cites W2001305984 @default.
• W2065994067 cites W2004903254 @default.
• W2065994067 cites W2012815053 @default.
• W2065994067 cites W2013440762 @default.
• W2065994067 cites W2015144518 @default.
• W2065994067 cites W2019591400 @default.
• W2065994067 cites W2027273899 @default.
• W2065994067 cites W2027307612 @default.
• W2065994067 cites W2032446812 @default.
• W2065994067 cites W2035790175 @default.
• W2065994067 cites W2036240062 @default.
• W2065994067 cites W2036852614 @default.
• W2065994067 cites W2051209381 @default.
• W2065994067 cites W2059214821 @default.
• W2065994067 cites W2061123442 @default.
• W2065994067 cites W2061359400 @default.
• W2065994067 cites W2062237037 @default.
• W2065994067 cites W2070896217 @default.
• W2065994067 cites W2074956690 @default.
• W2065994067 cites W2078664120 @default.
• W2065994067 cites W2090694793 @default.
• W2065994067 cites W2095196658 @default.
• W2065994067 cites W2102052455 @default.
• W2065994067 cites W2112137363 @default.
• W2065994067 cites W2146336482 @default.
• W2065994067 cites W2950266633 @default.
• W2065994067 cites W2950428880 @default.
• W2065994067 cites W2950827678 @default.
• W2065994067 cites W2951408969 @default.
• W2065994067 cites W4232235565 @default.
• W2065994067 cites W4238491222 @default.
• W2065994067 doi "https://doi.org/10.1021/ic048376r" @default.
• W2065994067 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15877421" @default.
• W2065994067 hasPublicationYear "2005" @default.
• W2065994067 type Work @default.
• W2065994067 sameAs 2065994067 @default.
• W2065994067 citedByCount "53" @default.
• W2065994067 countsByYear W20659940672012 @default.
• W2065994067 countsByYear W20659940672013 @default.
• W2065994067 countsByYear W20659940672014 @default.
• W2065994067 countsByYear W20659940672015 @default.
• W2065994067 countsByYear W20659940672016 @default.
• W2065994067 countsByYear W20659940672017 @default.
• W2065994067 countsByYear W20659940672018 @default.
• W2065994067 countsByYear W20659940672020 @default.
• W2065994067 countsByYear W20659940672021 @default.
• W2065994067 crossrefType "journal-article" @default.
• W2065994067 hasAuthorship W2065994067A5011274974 @default.
• W2065994067 hasAuthorship W2065994067A5017888744 @default.
• W2065994067 hasAuthorship W2065994067A5083979016 @default.
• W2065994067 hasConcept C116569031 @default.
• W2065994067 hasConcept C121332964 @default.
• W2065994067 hasConcept C161790260 @default.
• W2065994067 hasConcept C170493617 @default.
• W2065994067 hasConcept C178790620 @default.
• W2065994067 hasConcept C181500209 @default.
• W2065994067 hasConcept C184779094 @default.
• W2065994067 hasConcept C185592680 @default.
• W2065994067 hasConcept C192468462 @default.
• W2065994067 hasConcept C2776303508 @default.
• W2065994067 hasConcept C2776568683 @default.
• W2065994067 hasConcept C2779627003 @default.
• W2065994067 hasConcept C32891209 @default.
• W2065994067 hasConcept C55493867 @default.
• W2065994067 hasConcept C62520636 @default.
• W2065994067 hasConcept C71240020 @default.
• W2065994067 hasConcept C74561354 @default.
• W2065994067 hasConcept C75473681 @default.
• W2065994067 hasConcept C8010536 @default.
• W2065994067 hasConcept C91881484 @default.
• W2065994067 hasConcept C95503338 @default.
• W2065994067 hasConceptScore W2065994067C116569031 @default.
• W2065994067 hasConceptScore W2065994067C121332964 @default.
• W2065994067 hasConceptScore W2065994067C161790260 @default.
• W2065994067 hasConceptScore W2065994067C170493617 @default.
• W2065994067 hasConceptScore W2065994067C178790620 @default.
• W2065994067 hasConceptScore W2065994067C181500209 @default.
• W2065994067 hasConceptScore W2065994067C184779094 @default.
• W2065994067 hasConceptScore W2065994067C185592680 @default.
• W2065994067 hasConceptScore W2065994067C192468462 @default.
• W2065994067 hasConceptScore W2065994067C2776303508 @default.
• W2065994067 hasConceptScore W2065994067C2776568683 @default.
• W2065994067 hasConceptScore W2065994067C2779627003 @default.
• W2065994067 hasConceptScore W2065994067C32891209 @default.
• W2065994067 hasConceptScore W2065994067C55493867 @default.
• W2065994067 hasConceptScore W2065994067C62520636 @default.
• W2065994067 hasConceptScore W2065994067C71240020 @default.

• next