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- W2066007303 abstract "This paper describes the room temperature, gas phase reaction of NO2, excited by various cw visible lasers, with CO to form NO and CO2. The distilled CO2 product is detected by laser-induced fluorescence. Using this technique, and previously measured relaxation rates, the determined reaction rate constant with 4880 Å excitation is kR=3.2±1.2×10−1 5 cc/molecule sec. The observed dependences on laser intensity and reactant concentration are in agreement with a proposed mechanism in which NO2*+CO→NO+CO2 is the main step. Other possible mechanisms are found to disagree with experimental evidence. kR is found to increase smoothly by a factor of 10 as the exciting wavelength is decreased from 6125 to 4579 Å. This behavior is compared to a model in which RRK theory predicts reactivity and a step-ladder model describes relaxation. Using this RRK model fit, the observed activation energy is 1.8±0.2 eV, which appears to be 0.3–0.7 eV higher than the thermal energy barrier." @default.
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- W2066007303 date "1978-02-01" @default.
- W2066007303 modified "2023-09-27" @default.
- W2066007303 title "Analysis of the laser-stimulated reaction: NO2*+CO→NO+CO2" @default.
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- W2066007303 doi "https://doi.org/10.1063/1.435798" @default.
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