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- W2066020159 abstract "The gadolinium oxoalkoxide [Gd6(μ4-O)(OC2H4OMe)16] was obtained by reaction between gadolinium chips and 2-methoxyethanol or by alcohol interchange reaction from [Gd5(μ5-O)(OPri)13]. Its structure results from the self-assembly of two trinuclear units via a μ4-oxo ligand having tetrahedral stereochemistry. The gadolinium atoms are seven-and eight-coordinate. Four different coordination modes of the 2-methoxyethoxide ligands are observed, with Gd-O bond lengths ranging from 2.152(9) to 2.674(8) Å, the order of variation being GdOR < Gd-μ4-O < Gd-μ-OR < Gd-μ3-OR < GdO(ether)." @default.
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- W2066020159 date "1996-04-01" @default.
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- W2066020159 title "Building of lanthanide oxoalkoxides: Synthesis and molecular structure of [Gd6(μ4-O)(μ3,η2-OR)4(R,η2-OR)6(μν2-OR)2(OR)4] (R = C2H4OMe)" @default.
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- W2066020159 doi "https://doi.org/10.1016/0277-5387(95)00343-6" @default.
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